推荐：4-安基-2,3,5,6-四弗三弗甲本 97%

别名:2,3,5,6-四氟-4-三氟甲基苯胺

线性分子式:CF3C6F4NH2

CAS号:651-83-2

分子量:233.09

Beilstein:2657893

MDL编号:MFCD00091518

PubChem化学物质编号:329768293

NACRES:NA.22

属性
质量水平
100

检测方案
97%

形式
liquid

reaction suitability
reaction type: C-C Bond Formation
reagent type: catalyst
reaction type: C-H Activation

折射率
n20/D 1.431 (lit.)
n20/D 1.432

bp
186 °C (lit.)

密度
1.662 g/mL at 25 °C
1.687 g/mL at 25 °C (lit.)

SMILES string
Nc1c(F)c(F)c(c(F)c1F)C(F)(F)F

InChI
1S/C7H2F7N/c8-2-1(7(12,13)14)3(9)5(11)6(15)4(2)10/h15H2

InChI key
FJOACTZFMHZHSC-UHFFFAOYSA-N

说明
其他说明
Acidic amides are superior directing groups for promoting C-H activation reactions with both Pd(0)/PR3 and Pd(II) catalysts.[1]

Used in the Preparation of
Lactams via palladium-catalyzed olefination of arylamides with benzylacrylate, followed by 1,4-conjugate addition[2]
N-(fluorinated aryl)benzamides as substrates for regioselective C-H amination reactions with O-benzoylhydroxylamines[3]
Substituted succinimides via palladium-catalyzed carbonylation of N-aryl amides[4]
N-aryl cyclopropanecarboxamide substrates and various amino acid ligands for palladium-catalyzed C-H activation of cyclopropanes

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发表刊物        影响因子           奖励金额
SCI期刊杂志      1.0≤1F＜3.0          200元
SCI期刊杂志      3.0≤1F＜6.0          400元
SCI期刊杂志      6.0≤1F＜10.0         600元
SCI期刊杂志      1F≥10                1000元